I believe any selectable stats back gear will offer vipers/sinister, but I could be wrong. Unfortunately no, even the HOT ascended back item collections don't offer this (warmaster's, scholar's, lightbringer's packs and even the luminate's backplate). The easiest way for the back item is through the LS3 maps. 8. blackxxwolf3.
The legendary weapon kit is only a kit, and it only allows you to craft four specific legendary weapons. You can click on the eye on the offering to see the list. If you're going to make a legendary it will save you a good amount of gold, so it's probably worth it. In fact, if you're going to make a legendary it's probably the best bang for the Infusing and Attuning are mutually exclusive. A ring can be either, or both. The process for Infusing is exactly as @Dzjudz.9142 stated; while it can be a loot drop, it can also be done explicitly. Attuned is a different process, and can be preformed on a infused or regular ascended ring.
Throw this into the Mystic Forge: The item you're stat changing. 5 Globs of Ectoplasm. 1 Anthology of Heroes (bought from Miyani) The exotic Inscription (for weapons) or Insignia (armor) of the stat you want to change to. That last one is the only difficult part. For Viper's, you'll need to buy the recipe for a Viper's Orichalcum Imbued
3. Bandit Coin Purse (20-slot bag) The Bandit Coin Purse requires that players make it to the Silverwastes, which isn’t exactly a new player friendly zone, but it’s one of the quickest bags to get in GW2 since all it requires is unlocking 19 bandit weapon skins to complete the “Bandit Weapons Specialist” achievement.
limit it to level 80 only. select the 3 stats you want the item to include (power, precision, ferocity for power dps gear for example) search and sort by price. buy the gear that is the cheapest but with the stats you need. An armor item for a power dps build should cost around 30-40 silver. trinkets around 1-2g. 7q45f1.
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    • guild wars 2 how to get ascended gear